SCHOOL OF CHEMICAL ENGINEERING
师资队伍
Teachers查询:
教授
祝新利
现任职称/职务:化学工艺系 教授通讯地址:天津大学 化工学院化学工艺系 北洋园校区54楼
电子邮箱:xinlizhu@tju.edu.cn
办公电话:022-
论著专利:
在JACS, J Catal, ACS Catal, Appl Catal B等期刊发表SCI收录论文130余篇,SCI源期刊引用5000余次(请参考https://www.webofscience.com/wos/author/rid/A-7328-2011)。
部分近期论文:
65. Wang J., Liu T.S., Han J.Y., Wang H., Zhu X.L.*, Ge Q.F.* Theoretical investigation on the promotional role of Ag for reverse water-gas shift reaction on Ni catalysts during CO2 reduction, International Journal of Hydrogen Energy, 2024, In press. DOI: 10.1016/j.ijhydene.2024.05.088
64. Bi W.L.#, Zhang R.Y.#, Ge Q.F., Zhu X.L.* Supported Inverse MnOx/Pt Catalysts Facilitate Reverse Water Gas Shift Reaction, Catalysts, 2024, 14, 456. DOI: 10.3390/catal14070456
63. Bi W.L.#, Wang J.#, Zhang R.Y., Ge Q.F., Zhu X.L.* Tuning Interfacial Sites of WOx/Pt for Enhancing Reverse Water Gas Shift Reaction, ACS Catalysis, 2024, 14, 11205-11217. DOI: 10.1021/acscatal.4c02341
62. Yang Z.J., Ge Q.F., Zhu X.L.* Heteroatom Lewis acid zeolites: synthesis, characterization and application in the conversion of biomass-derived oxygenates, Green Chemistry, 2024, 26, 8068-8099. DOI: 10.1039/D4GC00985A
61. Qin Y.Y., Li L.W., Liu H.X., Han J.Y., Wang H., Zhu X.L.*, Ge Q.F.* Anionic oxyl radical formed on CrVI-oxo anchored on the defect site of the UiO-66 node facilitates methane to methanol conversion, Journal of Chemical Physics, 2024, 160, 134701. DOI: 10.1063/5.020175360. Liu H.X., Qin Y.Y., Li L.W., Wang H., Zhu X.L.*, Ge Q.F.* CH3 radical-mediated direct methane to methanol conversion over CuO supported on rutile oxides, Journal of Catalysis, 2024, 431, 115388. DOI: 10.1016/j.jcat.2024.115388
59. Liu
Z.H.#, Guo Y.H.#, Wang H., Zhu X.L.* Role of Na in the stability enhancement of CeO2 catalysts for ketonization of propionic acid, Applied Catalysis A General,
2024, 672, 119593. DOI: 10.1016/j.apcata.2024.119593
58. Zhao
Y.T., Fontillas N., Wang H., Zhu X.L.*,
Mei D.H., Ge Q.F.* Single Pd Atom−In2O3 Catalyzes Production of CH3CH2OH from Atom-Economic C−C
Coupling of HCHO and CH4, ACS Catalysis, 2024, 14, 1714-1724.
DOI: 10.1021/acscatal.3c05163
57. Yang
Z.J., Yu Q., Wang H., Ge Q.F., Zhu X.L.* Ketonization of propionic acid over TS-1 and Ti-Beta zeolites: Mechanism and
effects of topology and hydrophobicity, Journal of Catalysis, 2024, 429,
115247. DOI: 10.1016/j.jcat.2023.115247
56. Ding S.N., Zhu X.L.* Tuning Strong Metal-Support Interactions for Enhancing Direct
Deoxygenation of Biomass-Lignin Derived Phenolics, ChemCatChem,
2024, 16, e202301552. DOI: 10.1002/cctc.202301552
55. Wang Y.J., Zhu X.L.* Highly dispersed Ni-Cu/SiO2 synthesized by sol-gel method for prompting direct deoxygenation of m-cresol to toluene, Chemical Industry and Engineering Progress (化工进展), 2024, 43(7), 3824-3833. DOI: 10.16085/j.issn.1000-6613.2023-1009
54. Huang J., Wang H., Han J.Y., Zhu X.L.* Ketonization of propionic acid on potassium-doped anatase TiO2 catalysts, Journal of Chemical Engineering of Chinese Universities (高校化学工程学报), 2024, 38, 459-467. DOI: https://link.cnki.net/urlid/33.1141.TQ.20240430.1332.008
53. Wang
Y.J., Wang H., Han J.Y., Ge Q.F.*, Zhu
X.L.* Enhancing direct
deoxygenation of m-cresol to toluene through inhibiting C-C hydrogenolysis via
alloying Ni with Cu, Chemical
Engineering Research and Design, 2023, 199, 49-60. DOI: 10.1016/j.cherd.2023.09.023
52. Huang
J.#, Li L.W.#, Wu X.X., Guo Y.H., Yang Z.J., Wang H., Ge
Q.F., Zhu X.L.* Crystal facet
dependence of the ketonization of propionic acid on anatase TiO2, Catalysis Science Technology,
2023, 13, 5924-5937. DOI: 10.1039/d3cy00917c
51. Liu
H.X., Li L.W., Qin Y.Y., Wang H., Zhu X.L.*, Ge Q.F.* Synergetic C–H bond activation and C–O
formation on CuOx facilities facile conversion of methane to
methanol. Applied Surface Science, 2023, 627, 157283. DOI: 10.1016/j.apsusc.2023.157283
50. Li L.W., Liu H.X., Qin Y.Y., Wang H., Han
J.Y., Zhu X.L.*, Ge Q.F.* Tracking
Atomic Diffusion in Surface and Bulk CuO via Neural Network-Based Molecular
Dynamics. Journal of Physical Chemistry C, 2023, 127, 6948-6958.
DOI: 10.1021/acs.jpcc.3c00404
49. Wu B.W.#, Li L.W.#, Wang H., Han J.Y., Zhu X.L.* Ge Q.F.* Role of MoOx/Ni(111) Interfacial Sites in Direct
Deoxygenation of Phenol toward Benzene. Catalysis Science Technology, 2023, 13,
2201-2211. DOI: 10.1039/D2CY01529C
48. Wu X.X., Liu C.J., Wang H., Ge Q.F., Zhu X.L.* Origin of strong metal-support interactions
between Pt and anatase TiO2 facets for hydrodeoxygenation of
m-cresol on Pt/TiO2 catalysts. Journal of Catalysis, 2023, 418, 203-215. DOI: 10.1016/j.jcat.2023.01.023
47. Li L.W., Liu H.X., Qin Y.Y., Wang H., Han J.Y., Zhu X.L.* Ge Q.F.* Coupled oxygen desorption and structural reconstruction
accompanying reduction of copper oxide. Journal of Chemical Physics, 2023, 158, 054702. DOI: 10.1063/5.0136537
46. Qin Y.Y., Liu H.X., Li L.W., Han J.Y., Wang H., Zhu X.L.* Ge Q.F.* Hydroperoxyl-mediated C-H bond activation on Cr
single atom catalyst: An alternative to the Fenton mechanism. Journal of Catalysis, 2023, 417, 323-333. DOI: 10.1016/j.jcat.2022.12.017
45. Zhang C., Zhang R.Y., Liu Y.X, Wu X.X., Wang H., Ge Q.F., Zhu. X.L.* Blocking Methanation during Reverse Water Gas
Shift Reaction on Ni/SiO2 Catalysts by Surface Ag. ChemCatChem,
2023, 15, e202201284. DOI: 10.1002/cctc.202201284
44. Tan C.X., Liu H.X., Qin Y.Y., Li L.W., Wang H., Zhu X.L.* Ge Q.F.* Correlation between the Properties of Surface
Lattice Oxygen on NiO and Its Reactivity and Selectivity towards the Oxidative
Dehydrogenation of Propane. ChemPhysChem, 2023, 24, e202200539. DOI: 10.1002/cphc.202200539
43. Wei A.L., Zhang R.Y., Qin Y.Y., Wang H., Zhu X.L.* Ge Q.F.* . Journal
of Physical Chemistry C, 2022, 126, 18078-18089. DOI: (Front Cover)
42. Zhang R.Y., Ge Q.F., Zhu X.L.* Combining reverse water gas shift with gas
fermentation for renewable liquid fuel synthesis. Chem Catalysis, 2022, 2, 2137-2139. DOI: 10.1016/j.checat.2022.08.011
41. Cui B.L., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Size-Dependent Strong Metal–Support Interactions of Rutile TiO2-Supported
Ni Catalysts for Hydrodeoxygenation of m-Cresol. Catalysts, 2022, 12, 955. DOI: 10.3390/catal12090955
40. Cui B.L., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Crystal-phase-depended strong metal-support interactions enhancing hydrodeoxygenation of m-cresol on Ni/TiO2 catalysts. Journal of Catalysis, 2022, 413, 880-890. DOI: 10.1016/j.jcat.2022.07.039
39. Liu Y.X., Li L.W., Zhang R.Y., Guo Y.H., Wang H., Ge Q.F., Zhu. X.L.* Synergetic enhancement of activity and
selectivity for reverse water gas shift reaction on Pt-Re/SiO2 catalysts. Journal of CO2 Utilization, 2022, 63, 102128. DOI: 10.1016/j.jcou.2022.102128
38. Guo
Y.H.#, Qin Y.Y.#, Liu H.X., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F. CeO2 Facet-Dependent Surface
Reactive Intermediates and Activity during Ketonization of Propionic Acid. ACS
Catalysis, 2022, 12, 2998-3012. DOI: 10.1021/acscatal.1c05994 (Front Cover)
37. Yang
Z.J., Yu Q., Guo Y.H., Wu X.X., Wang H., Han J.Y., Ge Q.F., Zhu.X.L.* Effect of postsynthesis preparation methods
on catalytic performance of Ti-Beta zeolite in ketonization of propionic acid. Microporous
and Mesoporous Materials, 2022, 330, 111625. DOI: 10.1016/j.micromeso.2021.111625
36. Fu
D.S., Wu X.X., Cui B.L., Guo Y.H., Wang H., Han J.Y., Ge Q.F., Zhu
X.L.* Ru0.05Ce0.95O2 Solid Solution
Derived Ru Catalyst Enables Selective Hydrodeoxygenation of m-Cresol to Toluene. ChemCatChem,
2021, 13, 4814-4823. DOI: 10.1002/cctc.202101239
35. Zhang R.Y., Wei A.L., Zhu M., Wu X.X., Wang H., Zhu X.L.*, Ge Q.F., Journal of CO2 Utilization, 2021,
52, 101678.
34. Yu Q., Guo Y.H., Wu X.X., Yang Z.J., Wang H., Ge Q.F., Zhu X.L.* Ketonization of Propionic Acid on Lewis Acidic Zr-Beta Zeolite with Improved Stability and Selectivity. ACS Sustainable Chemistry Engineering, 2021, 9, 7982-7992. DOI: 10.1021/acssuschemeng.1c02290 (Front Cover)
33. Yang F.F., Komarneni M.R., Libretto N.J., Li L.W., Zhou W., Miller J.T., Ge Q.F., Zhu X.L.*, Resasco D.E.* Elucidating the Structure of Bimetallic NiW/SiO2 Catalysts and Its Consequences on Selective Deoxygenation of m-Cresol to Toluene. ACS Catalysis, 2021, 11, 2935-2948. DOI: 10.1021/acscatal.0c05560.
32. Zhu X.L.*, Faria J.A.*, Crossley S.P.* Preface: Selected
contributions from symposium of Catalytic Conversion of Biomass-Derived Oxygenates
in 258th ACS National meeting. Catalysis Today, 2021, 365, 142. DOI: 10.1016/j.cattod.2021.01.004.
31. Wu X.X., Ge Q.F.*, Zhu X.L.* Vapor phase hydrodeoxygenation of phenolic compounds on group 10 metal-based catalysts: Reaction mechanism and product selectivity control. Catalysis Today, 2021, 365, 143-161. DOI: 10.1016/j.cattod.2020.12.033.
30. Li L.S., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Balancing the Activity and Selectivity of Propane Oxidative Dehydrogenation on NiOOH (001) and (010). Transactions of Tianjin University (天津大学学报英文版), 2020, 26, 341-351. DOI: 10.1007/s12209-020-00267-3. (Front Cover)
29. Guo Y.H., Yu Q., Fang H.S., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Ce-UiO-66 Derived CeO2 Octahedron Catalysts for Efficient Ketonization of Propionic Acid, Industrial & Engineering Chemistry Research, 2020, 59, 17269-17278. DOI: 10.1021/acs.iecr.0c01238.
28. Wu X.X., Sun Q.Q., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Effect of acid-metal balance of bifunctional Pt/Beta catalysts on vapor phase hydrodeoxygenation of m-cresol, Catalysis Today, 2020, 355, 43-50, DOI: 10.1016/j.cattod.2019.04.039.
27. Zhu M., Ge Q.F., Zhu X.L.* Catalytic Reduction of CO2 to CO via Reverse Water Gas Shift Reaction: Recent Advances in Design of Active and Selective Supported Metal Catalysts, Transactions of Tianjin University (天津大学学报英文版), 2020, 26, 172-187. DOI:10.1007/s12209-020-00246-8.
26. Li L.W., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* A density functional theory study on reduction-induced structural transformation of copper-oxide-based oxygen carrier, Journal of Chemical Physics, 2020, 152, 054709. DOI: 10.1063/1.5137906.
25. Zhao J.K., Cui C.N., Wang H., Han J.Y., Zhu X.L.* Ge Q.F.* Anisotropic N-Modification of the Mo4 Ensemble for Efficient Ammonia Synthesis on Molybdenum Nitrides. Journal
of Physical Chemistry C, 2020, 124 (1), 616-624. DOI: 10.1021/acs.jpcc.9b09405.
24. Yang F.F., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Influence of Re addition to Ni/SiO2 catalyst on the reaction network and deactivation during hydrodeoxygenation of m-cresol, Catalysis Today, 2020, 347, 79-86. DOI: 10.1016/j.cattod.2018.04.073.
23. Yang F.F., Libretto N.J., Komarneni M., Zhou W., Miller J.T., Zhu X.L.*, Resasco D.E.* Enhancement of m-Cresol Hydrodeoxygenation Selectivity on Ni Catalysts by Surface Decoration of MoOx Species, ACS Catalysis, 2019, 9, 7791-7800. DOI: 10.1021/acscatal.9b01285.
22. Cao J.P., Ding S., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Conversion of C2-4 Carboxylic Acids to Hydrocarbons on HZSM-5: Effect of Carbon Chain Length. Industrial & Engineering Chemistry
Research, 2019, 58 (24), 10307-10316. DOI: 10.1021/acs.iecr.9b01755
21. Zhao Y.T., Wang H., Han J.Y., Zhu X.L.*, Mei D.H.*, Ge Q.F.* Simultaneous Activation of CH4 and CO2 for Concerted C−C Coupling at Oxide/Oxide Interfaces, ACS Catalysis, 2019, 9, 3187-3197. DOI: 10.1021/acscatal.9b00291.
20. Zhao J.K., Cui C.N., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Insights into the Mechanism of Ammonia Decomposition on Molybdenum Nitrides Based on DFT Studies, Journal of Physical Chemistry C, 2019, 123, 554-564. DOI: 10.1021/acs.jpcc.8b10101.
19. Yang F.F.#, Wang H.#, Han J.Y., Ge Q.F., Zhu X.L.* Enhanced selective deoxygenation of m-cresol to toluene on Ni/SiO2 catalysts derived from nickel phyllosilicate, Catalysis Today, 2019, 320, 149-156. DOI: 10.1016/j.cattod.2018.02.035.
18. Ding S., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F. Ketonization of Propionic Acid to 3-Pentanone over CexZr1-xO2Catalysts: The Importance of Acid-Base Balance, Industrial & Engineering Chemistry Research, 2018, 57 (50), 17086-17096. DOI: 10.1021/acs.iecr.8b04208.
17. Zhao X.Y.#, Wu X.X.#, Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Effect of Strong Metal-Support Interaction of Pt/TiO2 on Hydrodeoxygenation of m-Cresol, ChemistrySelect, 2018, 3, 10364-10370. DOI: 10.1002/slct.201801147.
16. Zhao Y.T., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Active Site Ensembles Enabled C−C Coupling of CO2 and CH4 for Acetone Production, Journal of Physical Chemistry C, 2018, 122, 9570-9577. DOI: 10.1021/acs.jpcc.8b02359.
15. Yang F.F., Liu D., Zhao Y.T., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Size Dependence of Vapor Phase Hydrodeoxygenation of m-Cresol on Ni/SiO2 Catalysts, ACS Catalysis, 2018, 8, 1672-1682. DOI: 10.1021/acscatal.7b04097.
14. Nie L., Peng B., Zhu X.L.* Vapor-Phase Hydrodeoxygenation of Guaiacol to Aromatics over Pt/HBeta: Identification of the Role of Acid Site and Metal Site on the Reaction Pathway, ChemCatChem, 2018, 10, 1064-1074. DOI:10.1002/cctc.201701413.
13. Wang X.F., Ding S., Wang H., Liu X., Han J.Y., Ge Q.F.*, Zhu X.L.* Conversion of propionic acid and 3-pentanone to hydrocarbons on ZSM-5 catalysts: reaction pathway and active site. Applied Catalysis A General, 2017, 545, 79-89. DOI:10.1016/j.apcata.2017.07.037 (feature article)
12. Liu D., Li G.F., Yang F.F., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Competition and Cooperation of Hydrogenation and Deoxygenation Reactions during Hydrodeoxygenation of Phenol on Pt(111). Journal of Physical Chemistry C, 2017, 121, 12249-12260. DOI: 10.1021/acs.jpcc.7b0304.
11. Ding S., Ge Q.F., Zhu X.L.* Research Progress in Ketonization of Biomass-derived Carboxylic Acids over Metal Oxides.Acta Chimica Sinica (化学学报), 2017, 75, 439-447.
10. Yang F.F., Liu D., Wang H., Liu X., Han J.Y., Ge Q.F.*, Zhu X.L.* Geometric and electronic effects of bimetallic Ni-Re catalysts for selective deoxygenation of m-cresol to toluene, Journal of Catalysis, 2017, 349, 84-97. DOI:10.1016/j.jcat.2017.01.001
9. Zhao Y.T., Cui C.N., Han J.Y., Wang H., Zhu X.L.*, Ge Q.F.*, Direct C-C Coupling of CO2 and the Methyl Group from CH4 Activation through Facile Insertion of CO2 into Zn-CH3 σ-bond, Journal of the American Chemical Society, 2016, 138, 10191-10198. DOI: 10.1021/jacs.6b04446
8. Wang H., Guo Y.G., Chang C.R., Zhu X.L.*, Liu X., Han J.Y., Ge Q.F.*, Enhancing tungsten oxide/SBA-15 catalysts for hydrolysis of cellobiose through doping ZrO2, Applied Catalysis A General, 2016, 523, 182-192. DOI: 10.1016/j.apcata.2016.06.006
7. Zhang X.P., Wang H.*, Liu X., Han J.Y., Zhu X.L.*, Ge Q.F. Effect of calcination and metal loading on the characteristics of Co/NaY catalyst for liquid-phase hydrogenation of ethyl lactate to 1,2-propanediol, Microporous Mesoporous Materials, 2016, 233, 184-193. DOI: 10.1016/j.micromeso.2016.04.015
6. Sun Q.Q., Chen G.Y., Wang H., Liu X., Han J.Y., Ge Q.F.*, Zhu X.L.* Insights into the Major Reaction Pathways of Vapor Phase Hydrodeoxygenation of m-Cresol on a Pt/HBeta Catalyst, ChemCatChem, 2016, 8, 551-561. DOI:10.1002/cctc.201501232(Back Cover)
5. Chen C., Zhu X.L.* Research Progress in Aromatic Hydrocarbons Production from Selective Direct Deoxygenation of Phenolics. Chemical Industry Engineering (化学工业与工程) 2016, 33, 26-32.
4. Chen C., Chen G.Y., Yang F.F., Wang H., Han J.Y., Ge Q.F.*, Zhu X.L.* Vapor phase hydrodeoxygenation and hydrogenation of m-cresol on silica supported Ni, Pd, Pt catalysts, Chemical Engineering Science, 2015, 135, 145-154. DOI:10.1016/j.ces.2015.04.054
3. Li G.F., Han J.Y., Wang H., Zhu X.L.*, Ge Q.F.*, Role of dissociation of phenol in its selective hydrogenation on Pt(111) and Pd(111), ACS Catalysis, 2015, 5, 2009-2015. DOI: 10.1021/cs501805y
2. Zhu X.L.*, Nie L., Lobban L.L., Mallinson R.G., Resasco D.E. Efficient Conversion of m‑Cresol to Aromatics on a Bifunctional Pt/HBeta Catalyst, Energy & Fuels, 2014, 28, 4104-4111. DOI: 10.1021/ef500768r
1. Zhu X.L.*, Hoang T., Lobban L.L., Mallinson R.G.* Partial oxidation of ethanol using a non-equilibrium plasma, International Journal of Hydrogen Energy, 2014, 39, 9047-9056.
2012年以前代表性论著:
1. Zhu X.L., Lobban L.L., Mallinson R.G., Resasco D.E.* Bifunctional transalkylation and hydrodeoxygenation of anisole over a Pt/HBeta catalyst, Journal of Catalysis 2011, 281, 21-29. (ESI高被引论文,期刊季度热点论文, Top cited papers in JCat 2011, 2014 Elsevier highlighted articles in catalysis area)
2. Zhu X.L., Shen M., Lobban L.L., Mallinson R.G.* Structural effects of Na promotion for high water gas shift activity on Pt-Na/TiO2, Journal of Catalysis 2011, 278, 123-132. (期刊季度热点论文)
3. Zhu X.L., Lobban L.L., Mallinson R.G., Resasco D.E.* Tailoring the mesopore structure of HZSM-5 to control product distribution in the conversion of propanal, Journal of Catalysis 2010, 271, 88-98.
4. Zhu X.L., Hoang T., Lobban L.L., Mallinosn R.G.* Plasma reforming of glycerol for synthesis gas production, Chemical Communications 2009, 2908-2910.
5. Zhu X.L., Hoang T., Lobban L.L., Mallinson R.G.* Low CO content hydrogen production from bio-ethanol using a combined plasma reforming-catalytic water gas shift reactor, Applied Catalysis B-Environmental 2010, 94, 311-317.
6. Zhu X.L., Huo P.P., Zhang Y.P., Cheng D.G., Liu C.J.* Structure and reactivity of plasma treated Ni/Al2O3 catalyst for CO2 reforming of methane, Applied Catalysis B-Environmental 2008, 81, 132-140. (期刊季度热点论文, Top cited papers in ApCatB 2008)