SCHOOL OF CHEMICAL ENGINEERING

教师登录系统

工号:

密码:

验证:

查询:

教授

祝新利

现任职称/职务:化学工艺系 教授
通讯地址:天津大学 化工学院化学工艺系 北洋园校区54楼
电子邮箱:xinlizhu@tju.edu.cn
办公电话:022-

论著专利:

在JACS, J Catal, ACS Catal, Appl Catal B等期刊发表SCI收录论文130余篇,SCI源期刊引用4600余次(请参考https://www.webofscience.com/wos/author/rid/A-7328-2011)。

 

部分近期论文:

58.  Liu H.X., Qin Y.Y., Li L.W., Wang H., Zhu X.L.*, Ge Q.F.* CH3 radical-mediated direct methane to methanol conversion over CuO supported on rutile oxides, Journal of Catalysis, 2024, 431, 115388. DOI: 10.1016/j.jcat.2024.115388

57.  Liu Z.H.#, Guo Y.H.#, Wang H., Zhu X.L.* Role of Na in the stability enhancement of CeO2 catalysts for ketonization of propionic acid, Applied Catalysis A General, 2024, 672, 119593. DOI: 10.1016/j.apcata.2024.119593

56.  Zhao Y.T., Fontillas N., Wang H., Zhu X.L.*, Mei D.H., Ge Q.F.*  Single Pd Atom−In2O3 Catalyzes Production of CH3CH2OH from Atom-Economic C−C Coupling of HCHO and CH4, ACS Catalysis, 2024, 14, 1714-1724. DOI: 10.1021/acscatal.3c05163

55.  Yang Z.J., Yu Q., Wang H., Ge Q.F., Zhu X.L.* Ketonization of propionic acid over TS-1 and Ti-Beta zeolites: Mechanism and effects of topology and hydrophobicity, Journal of Catalysis, 2024, 429, 115247. DOI: 10.1016/j.jcat.2023.115247

54.  Ding S.N., Zhu X.L.* Tuning Strong Metal-Support Interactions for Enhancing Direct Deoxygenation of Biomass-Lignin Derived Phenolics, ChemCatChem, 2024, 16, e202301552. DOI: 10.1002/cctc.202301552

53.  Wang Y.J., Wang H., Han J.Y., Ge Q.F.*, Zhu X.L.* Enhancing direct deoxygenation of m-cresol to toluene through inhibiting C-C hydrogenolysis via alloying Ni with Cu, Chemical Engineering Research and Design, 2023, 199, 49-60. DOI: 10.1016/j.cherd.2023.09.023

52.  Huang J.#, Li L.W.#, Wu X.X., Guo Y.H., Yang Z.J., Wang H., Ge Q.F., Zhu X.L.* Crystal facet dependence of the ketonization of propionic acid on anatase TiO2, Catalysis Science Technology, 2023, 13, 5924-5937. DOI: 10.1039/d3cy00917c

51.  Liu H.X., Li L.W., Qin Y.Y., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Synergetic C–H bond activation and C–O formation on CuOx facilities facile conversion of methane to methanol. Applied Surface Science, 2023, 627, 157283. DOI: 10.1016/j.apsusc.2023.157283

50.   Li L.W., Liu H.X., Qin Y.Y., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Tracking Atomic Diffusion in Surface and Bulk CuO via Neural Network-Based Molecular Dynamics. Journal of Physical Chemistry C, 2023, 127, 6948-6958. DOI: 10.1021/acs.jpcc.3c00404

49.  Wu B.W.#, Li L.W.#, Wang H., Han J.Y., Zhu X.L.* Ge Q.F.* Role of MoOx/Ni(111) Interfacial Sites in Direct Deoxygenation of Phenol toward Benzene. Catalysis Science Technology, 2023, 13, 2201-2211. DOI: 10.1039/D2CY01529C

48.  Wu X.X., Liu C.J., Wang H., Ge Q.F., Zhu X.L.* Origin of strong metal-support interactions between Pt and anatase TiO2 facets for hydrodeoxygenation of m-cresol on Pt/TiO2 catalystsJournal of Catalysis, 2023, 418, 203-215. DOI: 10.1016/j.jcat.2023.01.023

47.  Li L.W., Liu H.X., Qin Y.Y., Wang H., Han J.Y., Zhu X.L.* Ge Q.F.* Coupled oxygen desorption and structural reconstruction accompanying reduction of copper oxide. Journal of Chemical Physics, 2023, 158, 054702. DOI:  10.1063/5.0136537

46.  Qin Y.Y., Liu H.X., Li L.W., Han J.Y., Wang H., Zhu X.L.* Ge Q.F.* Hydroperoxyl-mediated C-H bond activation on Cr single atom catalyst: An alternative to the Fenton mechanism. Journal of Catalysis, 2023, 417, 323-333. DOI: 10.1016/j.jcat.2022.12.017

45.  Zhang C., Zhang R.Y., Liu Y.X, Wu X.X., Wang H., Ge Q.F., Zhu. X.L.* Blocking Methanation during Reverse Water Gas Shift Reaction on Ni/SiO2 Catalysts by Surface Ag.  ChemCatChem, 2023, 15, e202201284. DOI: 10.1002/cctc.202201284

44.  Tan C.X., Liu H.X., Qin Y.Y., Li L.W., Wang H., Zhu X.L.* Ge Q.F.* Correlation between the Properties of Surface Lattice Oxygen on NiO and Its Reactivity and Selectivity towards the Oxidative Dehydrogenation of Propane. ChemPhysChem, 2023, 24, e202200539. DOI: 10.1002/cphc.202200539

43.  Wei A.L., Zhang R.Y., Qin Y.Y., Wang H., Zhu X.L.* Ge Q.F.* . Journal of Physical Chemistry C, 2022, 126, 18078-18089. DOI: (Front Cover)

42.  Zhang R.Y., Ge Q.F., Zhu X.L.* Combining reverse water gas shift with gas fermentation for renewable liquid fuel synthesis. Chem Catalysis, 2022, 2, 2137-2139. DOI: 10.1016/j.checat.2022.08.011

41.  Cui B.L., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Size-Dependent Strong Metal–Support Interactions of Rutile TiO2-Supported Ni Catalysts for Hydrodeoxygenation of m-Cresol. Catalysts, 2022, 12, 955. DOI: 10.3390/catal12090955

40.  Cui B.L., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Crystal-phase-depended strong metal-support interactions enhancing hydrodeoxygenation of m-cresol on Ni/TiO2 catalysts. Journal of Catalysis, 2022, 413, 880-890. DOI: 10.1016/j.jcat.2022.07.039

39.  Liu Y.X., Li L.W., Zhang R.Y., Guo Y.H., Wang H., Ge Q.F., Zhu. X.L.* Synergetic enhancement of activity and selectivity for reverse water gas shift reaction on Pt-Re/SiO2 catalysts. Journal of CO2 Utilization, 2022, 63, 102128. DOI: 10.1016/j.jcou.2022.102128

38.  Guo Y.H.#, Qin Y.Y.#, Liu H.X., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.  CeO2 Facet-Dependent Surface Reactive Intermediates and Activity during Ketonization of Propionic Acid. ACS Catalysis, 2022, 12, 2998-3012. DOI: 10.1021/acscatal.1c05994 (Front Cover)

37.  Yang Z.J., Yu Q., Guo Y.H., Wu X.X., Wang H., Han J.Y., Ge Q.F., Zhu.X.L.*  Effect of postsynthesis preparation methods on catalytic performance of Ti-Beta zeolite in ketonization of propionic acid. Microporous and Mesoporous Materials, 2022, 330, 111625. DOI: 10.1016/j.micromeso.2021.111625

36.  Fu D.S., Wu X.X., Cui B.L., Guo Y.H., Wang H., Han J.Y., Ge Q.F., Zhu X.L.*  Ru0.05Ce0.95O2 Solid Solution Derived Ru Catalyst Enables Selective Hydrodeoxygenation of m-Cresol to Toluene. ChemCatChem, 2021, 13, 4814-4823. DOI: 10.1002/cctc.202101239

35.  Zhang R.Y., Wei A.L., Zhu M., Wu X.X., Wang H., Zhu X.L.*, Ge Q.F., Journal of CO2 Utilization, 2021, 52, 101678.

34.  Yu Q., Guo Y.H., Wu X.X., Yang Z.J., Wang H., Ge Q.F., Zhu X.L.* Ketonization of Propionic Acid on Lewis Acidic Zr-Beta Zeolite with Improved Stability and Selectivity. ACS Sustainable Chemistry Engineering, 2021, 9, 7982-7992. DOI: 10.1021/acssuschemeng.1c02290 (Front Cover)

33.  Yang F.F., Komarneni M.R., Libretto N.J., Li L.W., Zhou W., Miller J.T., Ge Q.F.,  Zhu X.L.*, Resasco D.E.* Elucidating the Structure of Bimetallic NiW/SiO2 Catalysts and Its Consequences on Selective Deoxygenation of m-Cresol to Toluene.  ACS Catalysis, 2021, 11, 2935-2948. DOI: 10.1021/acscatal.0c05560.

32.  Zhu X.L.*, Faria J.A.*, Crossley S.P.*  Preface: Selected contributions from symposium of Catalytic Conversion of Biomass-Derived Oxygenates in 258th ACS National meeting. Catalysis Today, 2021, 365, 142. DOI: 10.1016/j.cattod.2021.01.004.

31.  Wu X.X., Ge Q.F.*, Zhu X.L.* Vapor phase hydrodeoxygenation of phenolic compounds on group 10 metal-based catalysts: Reaction mechanism and product selectivity control. Catalysis Today, 2021, 365, 143-161. DOI: 10.1016/j.cattod.2020.12.033.

30.   Li L.S., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Balancing the Activity and Selectivity of Propane Oxidative Dehydrogenation on NiOOH (001) and (010). Transactions of Tianjin University (天津大学学报英文版), 2020, 26, 341-351. DOI: 10.1007/s12209-020-00267-3. (Front Cover)

29.  Guo Y.H., Yu Q., Fang H.S., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Ce-UiO-66 Derived CeO2 Octahedron Catalysts for Efficient Ketonization of Propionic Acid, Industrial & Engineering Chemistry Research, 2020, 59, 17269-17278. DOI: 10.1021/acs.iecr.0c01238.

28.  Wu X.X., Sun Q.Q., Wang H., Han J.Y., Ge Q.F., Zhu X.L.*  Effect of acid-metal balance of bifunctional Pt/Beta catalysts on vapor phase hydrodeoxygenation of m-cresol, Catalysis Today, 2020, 355, 43-50, DOI: 10.1016/j.cattod.2019.04.039.

27.  Zhu M., Ge Q.F., Zhu X.L.* Catalytic Reduction of CO2 to CO via Reverse Water Gas Shift Reaction: Recent Advances in Design of Active and Selective Supported Metal Catalysts, Transactions of Tianjin University (天津大学学报英文版), 2020, 26, 172-187. DOI:10.1007/s12209-020-00246-8.

26.  Li L.W., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.*  A density functional theory study on reduction-induced structural transformation of copper-oxide-based oxygen carrier, Journal of Chemical Physics, 2020, 152, 054709. DOI: 10.1063/1.5137906.

25.  Zhao J.K., Cui C.N., Wang H., Han J.Y., Zhu X.L.* Ge Q.F.* Anisotropic N-Modification of the Mo4 Ensemble for Efficient Ammonia Synthesis on Molybdenum Nitrides. Journal of Physical Chemistry C, 2020, 124 (1), 616-624. DOI: 10.1021/acs.jpcc.9b09405.

24.  Yang F.F., Wang H., Han J.Y., Ge Q.F., Zhu X.L.*  Influence of Re addition to Ni/SiO2 catalyst on the reaction network and deactivation during hydrodeoxygenation of m-cresol, Catalysis Today, 2020, 347, 79-86. DOI: 10.1016/j.cattod.2018.04.073.

23.  Yang F.F., Libretto N.J., Komarneni M., Zhou W., Miller J.T., Zhu X.L.*, Resasco D.E.*  Enhancement of m-Cresol Hydrodeoxygenation Selectivity on Ni Catalysts by Surface Decoration of MoOx Species, ACS Catalysis, 2019, 9, 7791-7800. DOI: 10.1021/acscatal.9b01285.

22.  Cao J.P., Ding S., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Conversion of C2-4 Carboxylic Acids to Hydrocarbons on HZSM-5: Effect of Carbon Chain Length. Industrial & Engineering Chemistry Research, 2019, 58 (24), 10307-10316. DOI: 10.1021/acs.iecr.9b01755

21.  Zhao Y.T., Wang H., Han J.Y., Zhu X.L.*, Mei D.H.*, Ge Q.F.*   Simultaneous Activation of CH4 and CO2 for Concerted C−C Coupling at Oxide/Oxide Interfaces, ACS Catalysis, 2019, 9, 3187-3197. DOI: 10.1021/acscatal.9b00291.

20.  Zhao J.K., Cui C.N., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.*  Insights into the Mechanism of Ammonia Decomposition on Molybdenum Nitrides Based on DFT Studies, Journal of Physical Chemistry C, 2019, 123, 554-564. DOI: 10.1021/acs.jpcc.8b10101.

19.  Yang F.F.#, Wang H.#, Han J.Y., Ge Q.F., Zhu X.L.* Enhanced selective deoxygenation of m-cresol to toluene on Ni/SiO2 catalysts derived from nickel phyllosilicate, Catalysis Today, 2019, 320, 149-156. DOI: 10.1016/j.cattod.2018.02.035.

18.  Ding S., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F. Ketonization of Propionic Acid to 3-Pentanone over CexZr1-xO2Catalysts: The Importance of Acid-Base Balance, Industrial & Engineering Chemistry Research, 2018, 57 (50), 17086-17096. DOI: 10.1021/acs.iecr.8b04208.

17.  Zhao X.Y.#, Wu X.X.#, Wang H., Han J.Y., Ge Q.F., Zhu X.L.*  Effect of Strong Metal-Support Interaction of Pt/TiO2 on Hydrodeoxygenation of m-Cresol,  ChemistrySelect, 2018, 3, 10364-10370. DOI: 10.1002/slct.201801147.

16.  Zhao Y.T., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Active Site Ensembles Enabled C−C Coupling of CO2 and CH4 for Acetone Production, Journal of Physical Chemistry C, 2018, 122, 9570-9577. DOI: 10.1021/acs.jpcc.8b02359.

15.  Yang F.F., Liu D., Zhao Y.T., Wang H., Han J.Y., Ge Q.F., Zhu X.L.* Size Dependence of Vapor Phase Hydrodeoxygenation of m-Cresol on Ni/SiO2 Catalysts, ACS Catalysis, 2018, 8, 1672-1682. DOI: 10.1021/acscatal.7b04097.

14.  Nie L., Peng B., Zhu X.L.* Vapor-Phase Hydrodeoxygenation of Guaiacol to Aromatics over Pt/HBeta: Identification of the Role of Acid Site and Metal Site on the Reaction Pathway, ChemCatChem, 2018, 10, 1064-1074. DOI:10.1002/cctc.201701413.

13.  Wang X.F., Ding S., Wang H., Liu X., Han J.Y., Ge Q.F.*, Zhu X.L.* Conversion of propionic acid and 3-pentanone to hydrocarbons on ZSM-5 catalysts: reaction pathway and active site. Applied Catalysis A General, 2017, 545, 79-89. DOI:10.1016/j.apcata.2017.07.037 (feature article)

12.  Liu D., Li G.F., Yang F.F., Wang H., Han J.Y., Zhu X.L.*, Ge Q.F.* Competition and Cooperation of Hydrogenation and Deoxygenation Reactions during Hydrodeoxygenation of Phenol on Pt(111). Journal of Physical Chemistry C, 2017, 121, 12249-12260. DOI: 10.1021/acs.jpcc.7b0304.

11.  Ding S., Ge Q.F., Zhu X.L.* Research Progress in Ketonization of Biomass-derived Carboxylic Acids over Metal Oxides.Acta Chimica Sinica (化学学报), 2017, 75, 439-447.

10.  Yang F.F., Liu D., Wang H., Liu X., Han J.Y., Ge Q.F.*, Zhu X.L.* Geometric and electronic effects of bimetallic Ni-Re catalysts for selective deoxygenation of m-cresol to toluene, Journal of Catalysis, 2017, 349, 84-97. DOI:10.1016/j.jcat.2017.01.001

9.  Zhao Y.T., Cui C.N., Han J.Y., Wang H., Zhu X.L.*, Ge Q.F.*, Direct C-C Coupling of CO2 and the Methyl Group from CH4 Activation through Facile Insertion of CO2 into Zn-CH3 σ-bond, Journal of the American Chemical Society, 2016, 138, 10191-10198. DOI: 10.1021/jacs.6b04446

8.  Wang H., Guo Y.G., Chang C.R., Zhu X.L.*, Liu X., Han J.Y., Ge Q.F.*, Enhancing tungsten oxide/SBA-15 catalysts for hydrolysis of cellobiose through doping ZrO2Applied Catalysis A General, 2016, 523, 182-192. DOI: 10.1016/j.apcata.2016.06.006

7.  Zhang X.P., Wang H.*, Liu X., Han J.Y., Zhu X.L.*, Ge Q.F. Effect of calcination and metal loading on the characteristics of Co/NaY catalyst for liquid-phase hydrogenation of ethyl lactate to 1,2-propanediol, Microporous Mesoporous Materials, 2016, 233, 184-193. DOI: 10.1016/j.micromeso.2016.04.015

6.  Sun Q.Q., Chen G.Y., Wang H., Liu X., Han J.Y., Ge Q.F.*, Zhu X.L.* Insights into the Major Reaction Pathways of Vapor Phase Hydrodeoxygenation of m-Cresol on a Pt/HBeta Catalyst, ChemCatChem, 2016, 8, 551-561. DOI:10.1002/cctc.201501232Back Cover)

5.  Chen C., Zhu X.L.* Research Progress in Aromatic Hydrocarbons Production from Selective Direct Deoxygenation of Phenolics. Chemical Industry Engineering (化学工业与工程) 2016, 33, 26-32.

4.  Chen C., Chen G.Y., Yang F.F., Wang H., Han J.Y., Ge Q.F.*, Zhu X.L.* Vapor phase hydrodeoxygenation and hydrogenation of m-cresol on silica supported Ni, Pd, Pt catalysts, Chemical Engineering Science, 2015, 135, 145-154. DOI:10.1016/j.ces.2015.04.054

3.  Li G.F., Han J.Y., Wang H., Zhu X.L.*, Ge Q.F.*, Role of dissociation of phenol in its selective hydrogenation on Pt(111) and Pd(111), ACS Catalysis, 2015, 5, 2009-2015. DOI: 10.1021/cs501805y

2.  Zhu X.L.*, Nie L., Lobban L.L., Mallinson R.G., Resasco D.E.  Efficient Conversion of m‑Cresol to Aromatics on a Bifunctional Pt/HBeta Catalyst, Energy & Fuels, 2014, 28, 4104-4111. DOI: 10.1021/ef500768r

1.  Zhu X.L.*, Hoang T., Lobban L.L., Mallinson R.G.* Partial oxidation of ethanol using a non-equilibrium plasma, International Journal of Hydrogen Energy, 2014, 39, 9047-9056.


 

2012年以前代表性论著:

1. Zhu X.L., Lobban L.L., Mallinson R.G., Resasco D.E.*  Bifunctional transalkylation and hydrodeoxygenation of anisole over a Pt/HBeta catalyst, Journal of Catalysis 2011, 281, 21-29. (ESI高被引论文,期刊季度热点论文, Top cited papers in JCat 2011, 2014 Elsevier highlighted articles in catalysis area)

2. Zhu X.L., Shen M., Lobban L.L., Mallinson R.G.*  Structural effects of Na promotion for high water gas shift activity on Pt-Na/TiO2, Journal of Catalysis 2011, 278, 123-132. (期刊季度热点论文)

3. Zhu X.L., Lobban L.L., Mallinson R.G., Resasco D.E.*  Tailoring the mesopore structure of HZSM-5 to control product distribution in the conversion of propanal, Journal of Catalysis 2010, 271, 88-98.

4. Zhu X.L., Hoang T., Lobban L.L., Mallinosn R.G.*  Plasma reforming of glycerol for synthesis gas production, Chemical Communications 2009, 2908-2910.

5. Zhu X.L., Hoang T., Lobban L.L., Mallinson R.G.*  Low CO content hydrogen production from bio-ethanol using a combined plasma reforming-catalytic water gas shift reactor, Applied Catalysis B-Environmental 2010, 94, 311-317.

6. Zhu X.L., Huo P.P., Zhang Y.P., Cheng D.G., Liu C.J.*  Structure and reactivity of plasma treated Ni/Al2O3 catalyst for CO2 reforming of methane, Applied Catalysis B-Environmental 2008, 81, 132-140. (期刊季度热点论文, Top cited papers in ApCatB 2008)