赵玉军

现任职称/职务：研究员
通讯地址：天津大学北洋校区54楼520
电子邮箱：yujunzhao@tju.edu.cn
办公电话：022-87401818

论著专利:

一、学术论文

(1)     Yaqi Yao, Xiaoqian Wu, Oliver Y. Gutiérrez, Jing Ji, Peng Jin, Shengnian Wang, Yan Xu, Yujun Zhao*, Shengping Wang, Xinbin Ma, Johannes A. Lercher, Roles of Cu⁺ and Cu⁰ sites in liquid-phase hydrogenation of esters on core-shell CuZnx@C catalysts, Appl. Catal. B-Environ., 2020, https://doi.org/10.1016/j.apcatb.2020.118698

(2)     Huijiang Huang, Bo Wang, Yue Wang, Yujun Zhao*, Shengping Wang, Xinbin Ma, Effect of sodium silicate on Cu/SiO2 catalyst for partial hydrogenation of dimethyl oxalate, Catal Today, 2019, https://doi.org/10.1016/j.cattod.2019.08.048

(3)     Yue Wang, Wenlong Yang, Shengping Wang, Yujun Zhao* and Xinbin Ma, Effect of surface hydroxyl group of ultra-small silica on the chemical states of copper catalyst for dimethyl oxalate hydrogenation, Catal Today, 2019, https://doi.org/10.1016/j.cattod.2019.06.031

(4)     Qiao Han, Mooeez Ur Rehman, Junhu Wang, Alexandre Rykov, Oliver Y. Gutiérrez, Yujun Zhao*, Shengping Wang, Xinbin Ma and Johannes A. Lercher, The synergistic effect between Ni sites and Ni-Fe alloy sites on hydrodeoxygenation of lignin-derived phenols, Appl. Catal. B: Environ., 2019, 253, 348-358. 

(5)     Xin Shang, Huijiang Huang, Qiao Han, Yan Xu, Yujun Zhao,* Shengping Wang and Xinbin Ma. Preferential synthesis of ethanol from syngas via dimethyl oxalate hydrogenation over an integrated catalyst, Chemical Communications, 2019,55, 5555-5558. (Cover Story). 

(6)     Jiaming Cheng, Yan Xu, Zhaopeng Liu, Zhenhua Li, Baowei Wang, Yujun Zhao,* Xinbin Ma, Mo-based catalyst supported on binary ceria-lanthanum solid solution for sulfur-resistant methanation: effect of La dopant, Ind. Eng. Chem. Res. 2019, 58 (5), 1803-1811. (Cover story).  

(7)     Mengyao Ouyang, Jian Wang, Bo Peng, Yujun Zhao,* Shengping Wang and Xinbin Ma, Effect of Ti on Ag catalyst supported on spherical fibrous silica for partial hydrogenation of dimethyl oxalate, Applied Surface Science, 466 (2019) 592–600.  

(8)     Yan Xu, Yan Wang, Chenguang Wu, Ying Zhang, Jun Nan, Haibin Yu, Yujun Zhao*, Structure effect of Ru/AC catalysts in hydrogenation of phthalates. Catal. Commun. 2019, 10.1016/j.catcom.2019.105825

(9)     Shengping Wang, Shihui Hou, Chao Wu, Yujun Zhao,* Xinbin Ma, RuCl3 anchored onto post-synthetic modification MIL-101(Cr)-NH2 as heterogeneous catalyst for hydrogenation of CO2 to formic acid, Chinese Chemical Letters, 2019, 30 (2), 398-402.  

(10)  Yujun Zhao*, Sijia Li, Zheng Wang, Shengnian Wang*, Shengping Wang, Xinbin Ma, New ZnCe catalyst encapsulated in SBA-15 in the production of 1,3-butadiene from ethanol, Chinese Chemistry Letter,2019, 31(2): 535-538

(11)  Yujun Zhao,* Xiaoqian Wu, Jiahua Zhou, Yue Wang, Shengping Wang, and Xinbin Ma, MOF-derived Cu@C catalyst for the liquid-phase hydrogenation of ester, Chem. Lett. 47(7), 883-886, 2018.  

(12)  Jiahua Zhou, Yujun Zhao,* Jian Zhang, Yue Wang, Oliver Y. Gutiérrez, Shengnian Wang, Zhengxiang Li, Peng Jin,* Shengping Wang, Xinbin Ma, Johannes A. Lercher, A Nitrogen-doped Hollow Silica Sphere Supported PtSn Nanocatalysts with Enhanced Dispersion towards Acetic Acid Hydrogenation, Chem. Commun., 2018, 54, 8818-8821. (Cover story)  

(13)  Yujun Zhao*, Bin Shan, Yue Wang, Jiahua Zhou, Shengping Wang and Xinbin Ma, An Effective CuZn-SiO2 Bimetallic Catalyst Prepared by Hydrolysis Precipitation Method for the Hydrogenation of Methyl Acetate to Ethanol, Ind Eng Chem Res. 57, 13(2018) 4526-4534 (Cover story) . 

(14)  Yujun Zhao, Ziyuan Guo, Haojie Zhang, Bo Peng, Yuxi Xu, Yue Wang, Jian Zhang, Yan Xu, Shengping Wang, and Xinbin Ma*, Hydrogenation of Diesters on Copper Catalyst Anchored on Ordered Hierarchically Porous Silica, J. Catal. 357(2018)223-237. 

(15)  Jia He, Yujun Zhao*, Yue Wang, Junhu Wang, Jian Zheng, Hanlei Zhang, Guangwen Zhou, Chongmin Wang, Shengping Wang and Xinbin Ma, A Fe₅C₂ nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation, Chem. Commun., 53 (2017) 5376-5379. (Cover story).  

(16)  Yujun Zhao*, Yaqing Zhang, Yue Wang, Jian Zhang, Yan Xu, Shengping Wang, Xinbin Ma, Structure evolution of mesoporous silica supported copper catalyst for dimethyl oxalate hydrogenation, Applied Catalysis A: General 539 (2017) 59-69.  

(17)  Yue Wang, Junyu Liao, Jian Zhang, Shengping Wang, Yujun Zhao* and Xinbin Ma, Hydrogenation of methyl acetate to ethanol by Cu/ZnO catalyst encapsulated in SBA-15, AIChE Journal, 63 (2017) 2839–2849.  

(18)  Yujun Zhao, Siming Li, Yue Wang, Bin Shan, Jian Zhang, Shengping Wang, Xinbin Ma*, Efficient tuning of surface copper species of Cu/SiO2 catalyst for hydrogenation of dimethyl oxalate to ethylene glycol, Chemical Engineering Journal, 2017, 113, 759–768.  

(19)  Yujun Zhao, Ziyuan Guo, Haojie Zhang, Yuxi Xu, Yue Wang, Jian Zhang, Yan Xu*, Shengping Wang, and Xinbin Ma*, Ordered mesoporous CuZn/HPS catalysts for the chemoselective hydrogenation of dimethyl adipate to 1, 6-hexanediol, Chem Lett, 46 (2017) 1079-1082.  

(20)  Guozhen Xu, Jian Zhang*, Shengping Wang, Yujun Zhao*, Xinbin Ma, Effect of thermal pretreatment on the surface structure of PtSn/SiO2 catalyst and its performance in acetic acid hydrogenation, Frontiers of Chemical Science and Engineering, 2016, 10(3):417-424.  

(21)  Guozhen Xu, Jian Zhang *, Shengping Wang, Yujun Zhao*, Xinbin Ma, A well fabricated PtSn/SiO₂ catalyst with enhanced synergy between Pt and Sn for acetic acid hydrogenation to ethanol, RSC Advances, 2016, 6, 51005 – 51013. 

(22)  Mengyao Ouyang, Yue Wang, Jian Zhang, Yujun Zhao*, Shengping Wang and Xinbin Ma, Three dimensional Ag/KCC-1 catalyst with hierarchical fibrous framework for the hydrogenation of dimethyl oxalate, RSC Advances, 2016, 6, 12788 – 12791. 

(23)  Yujun Zhao, Shuo Zhao, Yaochen Geng, Yongli Shen, Hairong Yue, Jing Lv, Shengping Wang and Xinbin Ma*, Ni-containing Cu/SiO2 catalyst for the chemoselective synthesis of ethanol via hydrogenation of dimethyl oxalate, Catalysis Today, 2016, 276: 28-35.  

(24)  Yanbo Song, Jian Zhang, Jing Lv, Yujun Zhao*, Xibin Ma, Hydrogenation of Dimethyl Oxalate over Copper based Catalysts: Acid-Base Properties and Reaction Paths, Ind Eng Chem Res. 2015; 54(10): 9699−9707. 

(25)  Siming Li, Yue Wang, Jian Zhang, Shengping Wang, Yan Xu, Yujun Zhao*, Xinbin Ma, Kinetics Study of Hydrogenation of Dimethyl Oxalate over Cu/SiO2Catalyst, Ind Eng Chem Res. 2015;54(4):1243-1250.  

(26)  Yan Xu, Qu Chen, Yujun Zhao*, Jing Lv, Zhenhua Li, Xinbin Ma*, Autocatalytic Kinetic Study of Dimethyl Oxalate Consecutive Hydrolysis. Ind Eng Chem Res. 2014;53(11):4207-4214. 

(27)  Yan Xu, Fan Wang, Qingfeng Hou,* Yujun Zhao,* Guosheng Ding and Xingguang Xu, Strategy for Synthesizing Novel Acetamidines as CO2-Triggered Switchable Surfactants via Acetimidates, Transactions of Tianjin University, 2019, 25 (3), 237-244.

(28)  Peng Jin*, Le Yang, Chang Liu, Muqing Chen, Qinghua Hou, Lanlan Li*, Yujun Zhao*, A comparative study on the N-heterocyclic carbene adducts of Ih-C60, D5h-C70 and Sc3N@Ih-C80, Physical Chemistry Chemical Physics Pccp, 2017, 19 (27), 17598. 

(29)  Peng Jin, Chang Liu, Ying Li, Lanlan Li, Yujun Zhao*, Th@C₇₆ Computational characterization of larger actinide endohedral fullerenes, International Journal of Quantum Chemistry, 2018, 118 (5).  

(30)  Yue Wang, Yujun Zhao, Jing Lv and Xinbin Ma*, Facile Synthesis of Cu@CeO2 and Its Catalytic Behavior for the Hydrogenation of Methyl Acetate to Ethanol, ChemCatChem, 2017, DOI: 10.1002/cctc.201700111.

(31)  Wei Zhou, Yujun Zhao, Shengping Wang, Xinbin Ma*, The Effect of Metal Properties on the Reaction Routes of Glycerol Hydrogenolysis over Platinum and Ruthenium Catalysts. Catalysis Today 298 (2017) 2-8.

(32)  Wei Zhou, Yujun Zhao, Yue Wang, Shengping Wang, and Xinbin Ma*, Glycerol Hydrogenolysis to 1,3-Propanediol on Tungstate/Zirconia-Supported Platinum: Hydrogen Spillover Facilitated by Pt(111) Formation, ChemCatChem 2016, 8, 3663 – 3671.  

(33)  S.P. Wang, S.S. Fan, Y.J. Zhao, L.J. Fan, S.Y. Liu, X.B Ma. Carbonation Condition and Modeling Studies of Calcium-Based Sorbent in the Fixed-Bed Reactor. Ind Eng Chem Res. 2014. doi10.1021/ie500789g

(34)  Y.L. Meng, T. Wang, S. Chen, Y.J. Zhao, X.B. Ma, J.L. Gong. Selective oxidation of methanol to dimethoxymethane on V2O5–MoO3/γ-Al2O3 catalysts. Appl. Catal. B, 2014; 160-161(0):161-172.

(35)  J.L. Gong, H.R. Yue, Y.J. Zhao, S. Zhao, L. Zhao, J. Lv, S.P. Wang, X.B. Ma, Synthesis of Ethanol via Syngas on Cu/SiO2 Catalysts with Balanced Cu0–Cu+ Sites, Journal of the American Chemical Society, 134 (2012) 13922-13925.

(36)  H.R. Yue, Y.J Zhao, S. Zhao, B. Wang, X.B. Ma, J.L. Gong, A copper-phyllosilicate core-sheath nanoreactor for carbon–oxygen hydrogenolysis reactions, Nat Commun, 4 (2013). 2339 doi10.1038/ncomms3339.

(37)  H.R. Yue, Y.J. Zhao, L. Zhao, J. Lv, S.P. Wang, J.L. Gong, X.B. Ma, Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability, AIChE Journal, 58 (2012) 2798-2809.

(38)  H.R. Yue, Y.J. Zhao, X.B. Ma, J.L. Gong, Ethylene glycol: properties, synthesis, and applications, Chem. Soc. Rev., 41 (2012) 4218-4244.

(39)  L. Zhao, Y.J. Zhao, S.P. Wang, H.R. Yue, B. Wang, J. Lv, X.B. Ma, Hydrogenation of Dimethyl Oxalate Using Extruded Cu/SiO2 Catalysts: Mechanical Strength and Catalytic Performance, Ind Eng Chem Res, 51 (2012) 13935-13943.

(40)  S. Zhao, H.R. Yue, Y.J. Zhao, B. Wang, Y.C. Geng, J. Lv, S.P. Wang, J.L. Gong, X.B. Ma, Chemoselective synthesis of ethanol via hydrogenation of dimethyl oxalate on Cu/SiO2: Enhanced stability with boron dopant, J Catal, 297 (2013) 142-150.

(41)  X.B. Ma, H.W. Chi, H.R. Yue, Y.J. Zhao, Y. Xu, J. Lv, S.P. Wang, J.L. Gong, Hydrogenation of dimethyl oxalate to ethylene glycol over mesoporous Cu-MCM-41 catalysts, AIChE Journal, 59 (2013) 2530-2539.

(42)  S.P. Wang, H.L. Shen, S.S. Fan, Y.J. Zhao, X.B. Ma, J.L. Gong, Enhanced CO2 adsorption capacity and stability using CaO-based adsorbents treated by hydration, AIChE Journal, 59 (2013) 3587-3593.

(43)  Y. Xu, W.J. Dou, Y.J. Zhao, G.X. Huang, X.B. Ma, Kinetics Study for Ion-Exchange-Resin Catalyzed Hydrolysis of Methyl Glycolate, Ind Eng Chem Res, 51 (2012) 11653-11658.

(44)  S.P. Wang, L. Zhao, W. Wang, Y.J. Zhao, G. Zhang, X.B. Ma, J.L. Gong, Morphology control of ceria nanocrystals for catalytic conversion of CO2 with methanol, Nanoscale, 5 (2013) 5582-5588.

(45)  Y.Y. Dong, S.Y. Huang, S.P. Wang, Y.J Zhao, J.L. Gong, X.B. Ma, Synthesis of Dimethyl Carbonate through Vapor-Phase Carbonylation Catalyzed by Pd-Doped Zeolites: Interaction of Lewis Acidic Sites and Pd Species, Chemcatchem, 5 (2013) 2174-2177.

(46)  S. Chen, Y.L. Meng, Y.J. Zhao, X.B. Ma, J.L. Gong, Selective Oxidation of Methanol to Dimethoxymethane over Mesoporous Al-P-V-O Catalysts, AIChE Journal, 59 (2013) 2587-2593.

(47)  S.P. Wang, X. Zhang, Y.J. Zhao, Y.D. Ge, J. Lv, B. Wang, X.B. Ma, Pd-Fe/α-Al2O3/cordierite monolithic catalysts for the synthesis of dimethyl oxalate: effects of calcination and structure, Front. Chem. Sci. Eng., 6 (2012) 259-269.

(48)  Y.D. Ge, Y.Y. Dong, S.P. Wang, Y.J. Zhao, J. Lv, X.B. Ma, Influence of crystalline phase of Li-Al-O oxides on the activity of Wacker-type catalysts in dimethyl carbonate synthesis, Front. Chem. Sci. Eng., 6 (2012) 415-422.

(49)  X.C. Gao, Y.J. Zhao, S.P. Wang, Y.L. Yin, B. Wang, X.B. Ma, A Pd-Fe/alpha-Al2O3/cordierite monolithic catalyst for CO coupling to oxalate, Chemical Engineering Science, 66 (2011) 3513-3522.

(50)  Y.J. Zhao, J. Zhou, J.G. Zhang, D.Y. Li, S.D. Wang, Selective hydrogenation of benzene to cyclohexene on a Ru/Al2O3/cordierite monolithic catalyst: Effect of mass transfer on the catalytic performance, Ind Eng Chem Res, 47 (2008) 4641-4647.

(51)  Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Liquid-phase selective hydrogenation of benzene to cyclohexene on Ru/Al2O3-ZrO2/cordierite monolithic catalysts, J Mol Catal a-Chem, 309 (2009) 35-39.

(52)  Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Preparation and Characterization of Ru/Al2O3/Cordierite Monolithic Catalysts for Selective Hydrogenation of Benzene to Cyclohexene, Catal Lett, 131 (2009) 597-605.

(53)  Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Monolithic Ru-based catalyst for selective hydrogenation of benzene to cyclohexene, Catal Commun, 9 (2008) 459-464.

(54)  J.G. Zhang, D.F. Li, Y.J. Zhao, Q.D. Kong, S.D. Wang, A Pd/Al2O3/cordierite monolithic catalyst for hydrogenation of 2-ethylanthraquinone, Catal Commun, 9 (2008) 2565-2569.

二、国内专利 

 (1)  赵玉军；徐艳；王岩；吴晨光, 一种邻苯二甲酸酯加氢催化剂及其制备方法与应用, 2019103581023 （2019.04.30）

(2)     赵玉军；韩巧；马新宾；王胜平, 一种介孔碳球负载镍铁合金纳米颗粒催化剂及其制备方法与应用, 2019103580459（2019.04.30）

(3)     赵玉军；尚鑫；王胜平；马新宾, 一种采用集成催化剂耦合催化草酸酯加氢制乙醇的方法, 2019103580891（2019.04.30）

(4)     赵玉军 欧阳梦瑶 马新宾 王胜平 草酸酯加氢制乙醇酸甲酯的多级孔纳米花结构Ag 催化剂， 201710522543.3 (2017.06.30)

(5)     赵玉军 郭子原 马新宾 王胜平 一种己二酸二甲酯气相加氢制备1,6-己二醇的方法 CN201710236004.3 （2017.04.12）

(6)     赵玉军 武晓倩 马新宾 王胜平 用于酯类液相加氢合成脂肪醇的铜碳催化剂及其制备方法 201810227833X （2018.03.20）

(7)     赵玉军 单宾 马新宾 王胜平  醋酸甲酯加氢生产乙醇的铜锌二氧化硅催化剂及其制备方法 201810207077.4 （2018.03.14）

(8)     赵玉军 周佳华 马新宾 王胜平 醋酸加氢制乙醇含氮二氧化硅空心球负载铂锡催化剂及制备 ZL201810258423.1 （授权  ）

(9)     张剑 许国贞 赵玉军 马新宾 王胜平 用于醋酸加氢生产乙醇的铂锡二氧化硅催化剂的制备方法 ZL201610266337.6（授权日：2018-10-26）

(10)  赵玉军 马新宾 王胜平 吕静 宋衍博 用于草酸酯加氢制乙醇的催化剂及制备方法 ZL201510535692.4 （授权）（2017.08.25）B01J23/72(2006.01)I

(11)  赵玉军 马新宾 王胜平 吕静 宋衍博 两段法草酸酯加氢制备乙醇的工艺  ZL201510535737.8（授权）（2017.04.12）C07C29/149(2006.01)I

(12)  赵玉军 吕静 马新宾  曹新园 王胜平 王保伟 李振花 徐艳        用于醋酸酯加氢制乙醇的催化剂及其制备方法        ZL201210475769.X（授权）IPC: B01J29/03(2006.01)I

(13)  吕静 赵玉军 马新宾 曹新园 王胜平 王保伟 李振花 徐艳  醋酸酯加氢制乙醇的方法    ZL201210475715.3（授权）IPC: C07C31/08(2006.01)I;

(14)  马新宾，吕静，赵玉军，王胜平，王保伟，李振花，徐艳，巩金龙. 用于草酸酯加氢制乙醇的催化剂及其制备方法与应. ZL201110227292.9（授权）B01J23/78(2006.01)I

(15)  马新宾，赵玉军，王胜平，赵国杰，余铭程，吕静，王保伟，李振花. 用于草酸酯加氢制乙二醇的催化剂及其制备方法. ZL 201010191578.1（授权）IPC: B01J23/76(2006.01)I

(16)  马新宾，赵玉军，岳海荣，王胜平，吕静，王保伟，李振花，徐艳.  用于草酸酯加氢制乙二醇的规整结构催化剂及其制备方法. ZL 201010207694.8（授权）IPC: B01J23/72(2006.01)I

(17)  马新宾，赵玉军，王保伟，吕静，王胜平，李振花，徐艳. 使用规整催化剂由CO气相偶联合成草酸酯的生产方法. ZL 201010191579.6（授权）

(18)  马新宾，高晓晨，赵玉军，王保伟，王胜平，吕静，李振花，徐艳. 由CO气相偶联合成草酸酯的规整催化剂及其制备方法. ZL 201010191580.9（授权）

(19)   王树东，赵玉军，周谨. 用于苯加氢制环己烯的整体催化剂及其制备方法. ZL200710064614.6（授权）

(20)  黄守莹; 马新宾; 闫冰; 王胜平; 赵玉军; 蒸氨法制备铜基催化剂及其在氧化羰基化合成烷基碳酸酯中的应用，CN201210594946.6

(21)  巩金龙; 孟亚利; 马新宾; 陈爽; 赵玉军; 王胜平; 甲醇选择性氧化合成二甲氧基甲烷的负载型氧化钼催化剂及应用， CN201210330499.3

(22)  吕静; 李振花; 马新宾; 王胜平; 赵玉军; 曹新原; 由氢氧化钙羰基化制备甲酸钙的连续生产工艺，CN201310061028.1

三、国际专利 

（1）Xinbin Ma, Yujun Zhao, Shengping Wang, Jing Lv, Baowei Wang, Zhenhua Li, Yan Xu, Copper hydrogenation catalyst, especially for converting oxalate to ethylene glycol, method of preparing the catalyst and applications thereof, US 13723221

（2）Xinbin Ma, Yujun Zhao, Baowei Wang, Shengping Wang, Jing Lv, Zhenhua Li, Monolithic structured catalyst for carbon monoxide gase-phase coupling to dialkyl oxalate & preparation method and application thereof, US 13701508

（3）Xinbin Ma, Jing Lv, Yujun Zhao, Shengping Wang, Baowei Wang, Zhenhua Li, Yan Xu, Gong jinlong, Catalyst for hydrogenation of oxalic ester to ethanol, method of preparing the catalyst, and method of using the same, US 9029285B2

（4）Xinbin Ma, Jing Lv, Yujun Zhao, Shengping Wang, Baowei Wang, Zhenhua Li, Yan Xu, Gong jinlong, Catalyst for ethanol production via hydrogenation of oxalate and preparation method and use thereof, EP2636448

（5）马新宾 赵玉军 王保伟 王胜平 吕静 李振花,ＣＯ気相カップリングによるシュウ酸塩の合成に用いるモノリス構造体触媒とその調製方法、およびそれを用いたシュウ酸塩の製造方法, JP 5947792

（6）Xinbin Ma, Yujun Zhao, Baowei Wang, Shengping Wang, Jing Lv, Zhenhua Li, Monolithic structured catalyst for carbon monoxide gase-phase coupling to dialkyl oxalate & preparation method and application thereof, IN 291884

（7）Xinbin Ma, Yujun Zhao, Shengping Wang, Jing Lv, Baowei Wang, Zhenhua Li, Yan Xu, Catalyst having monolithic structure for manufacturing ethylene glycol by oxalate hydrogenation, preparation method and application thereof, EP11797608.4

（8）Xinbin Ma, Yujun Zhao, Shengping Wang, Jing Lv, Baowei Wang, Zhenhua Li, Yan Xu, Catalyst having monolithic structure for manufacturing ethylene glycol by oxalate hydrogenation, preparation method and application thereof, IN 503/CHENP/2013

（9）Xinbin Ma, Jing Lv, Yujun Zhao, Shengping Wang, Baowei Wang, Zhenhua Li, Yan Xu, Gong jinlong, Catalyst for ethanol production via hydrogenation of oxalate and preparation method and use thereof, IN4616/CHENP/2013