SCHOOL OF CHEMICAL ENGINEERING

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副教授

赵玉军

现任职称/职务:副研究员
通讯地址:天津大学天南大联合楼B座401
电子邮箱:yujunzhao@tju.edu.cn
办公电话:13821663221(微信:liveforduty)

论著专利:

1. 发表论文 

1)    

1)      Jiahua Zhou, Yujun Zhao,* Jian Zhang, Yue Wang, Oliver Y. Gutiérrez, Shengnian Wang, Zhengxiang Li, Peng Jin,* Shengping Wang, Xinbin Ma, Johannes A. Lercher, Nitrogen-doped Hollow Silica Sphere Supported PtSn Nanocatalysts with Enhanced Dispersion towards Acetic Acid Hydrogenation, Chem. Commun., 2018, DOI: 10.1039/C8CC03649G.

2)      Yujun Zhao,* Xiaoqian Wu, Jiahua Zhou, Yue Wang, Shengping Wang, and Xinbin Ma MOF-derived Cu@C catalyst for the liquid-phase hydrogenation of ester, Chem. Lett. doi:10.1246/cl.180277, online at May 9, 2018.

3)      Yan Xu, Fan Wang, Qingfeng Hou,* Yujun Zhao,* Guosheng Ding and Xingguang Xu, Strategy for Synthesizing Novel Acetamidines as CO2-Triggered Switchable Surfactants via Acetimidates, Transactions of Tianjin University, 2018, DOI: 10.1007/s12209-018-0169-z.

4)      Yujun Zhao*, Bin Shan, Yue Wang, Jiahua Zhou, Shengping Wang and Xinbin Ma, An Effective CuZn-SiO2 Bimetallic Catalyst Prepared by Hydrolysis Precipitation Method for the Hydrogenation of Methyl Acetate to Ethanol, Ind Eng Chem Res. 57, 13, 4526-4534 (Cover story) IDS: GC1AH

5)      Yujun Zhao, Ziyuan Guo, Haojie Zhang, Bo Peng, Yuxi Xu, Yue Wang, Jian Zhang, Yan Xu, Shengping Wang, and Xinbin Ma*, Hydrogenation of Diesters on Copper Catalyst Anchored on Ordered Hierarchically Porous Silica, J. Catal. 357(2018)223-237. IDS: FU9JP

6)      Yujun Zhao, Ziyuan Guo, Haojie Zhang, Yuxi Xu, Yue Wang, Jian Zhang, Yan Xu*, Shengping Wang, and Xinbin Ma*, Ordered mesoporous CuZn/HPS catalysts for the chemoselective hydrogenation of dimethyl adipate to 1, 6-hexanediol, Chem Lett, 46 (2017) 1079-1082.

7)      Jia He, Yujun Zhao*, Yue Wang, Junhu Wang, Jian Zheng, Hanlei Zhang, Guangwen Zhou, Chongmin Wang, Shengping Wang and Xinbin Ma, A Fe5C2 nanocatalyst for the preferential synthesis of ethanol via dimethyl oxalate hydrogenation, Chem. Commun., 53 (2017) 5376-5379. (Cover story).

8)      Yujun Zhao*, Yaqing Zhang, Yue Wang, Jian Zhang, Yan Xu, Shengping Wang, Xinbin Ma, Structure evolution of mesoporous silica supported copper catalyst for dimethyl oxalate hydrogenation, Applied Catalysis A: General 539 (2017) 59-69.

9)      Yue Wang, Junyu Liao, Jian Zhang, Shengping Wang, Yujun Zhao* and Xinbin Ma, Hydrogenation of methyl acetate to ethanol by Cu/ZnO catalyst encapsulated in SBA-15, AIChE Journal, 63 (2017) 2839–2849.

10)    Yujun Zhao, Siming Li, Yue Wang, Bin Shan, Jian Zhang, Shengping Wang, Xinbin Ma*, Efficient tuning of surface copper species of Cu/SiO2 catalyst for hydrogenation of dimethyl oxalate to ethylene glycol, Chemical Engineering Journal, 2017, 113, 759–768.

11)    G.Z. Xu, J. Zhang*, S.P. Wang, Y.J. Zhao*, X.B. Ma, Effect of thermal pretreatment on the surface structure of PtSn/SiO2 catalyst and its performance in acetic acid hydrogenation, Frontiers of Chemical Science and Engineering, 2016, 10(3):417-424.

12)    G.Z. Xu, J. Zhang*, S.P. Wang, Y.J. Zhao*, X.B. Ma, A well fabricated PtSn/SiO2 catalyst with enhanced synergy between Pt and Sn for acetic acid hydrogenation to ethanol, RSC Advances, 2016, 6, 51005 – 51013.

13)    M.Y. Ouyang, Y. Wang, J.Zhang, Y.J. Zhao*, S.P. Wang and X.B. Ma, Three dimensional Ag/KCC-1 catalyst with hierarchical fibrous framework for the hydrogenation of dimethyl oxalate, RSC Advances, 2016, 6, 12788 – 12791

14)    Y.J. Zhao, S. Zhao, Y. Geng, Y.L Shen, H.R. Yue, J. Lv, S.P. Wang and X.B. Ma*, Ni-containing Cu/SiO2 catalyst for the chemoselective synthesis of ethanol via hydrogenation of dimethyl oxalate, Catalysis Today, 2016, 276: 28-35

15)    Y.B. Song, J. Zhang, J. Lv, Y.J. Zhao*, X.B. Ma, Hydrogenation of Dimethyl Oxalate over Copper based Catalysts: Acid-Base Properties and Reaction Paths, Ind Eng Chem Res. 2015; 54(10): 96999707.

16)    S.M. Li, Y. Wang, J. Zhang, S.P. Wang, Y. Xu, Y.J. Zhao*, X. B. Ma, Kinetics Study of Hydrogenation of Dimethyl Oxalate over Cu/SiO2Catalyst, Ind Eng Chem Res. 2015;54(4):1243-1250.

17)    Y. Xu, Q. Chen, Y.J. Zhao*, J. Lv, Z.H. Li, X.B. Ma*, Autocatalytic Kinetic Study of Dimethyl Oxalate Consecutive Hydrolysis. Ind Eng Chem Res. 2014;53(11):4207-4214.

18)    Yue Wang, Yujun Zhao, Jing Lv and Xinbin Ma*, Facile Synthesis of Cu@CeO2 and Its Catalytic Behavior for the Hydrogenation of Methyl Acetate to Ethanol, ChemCatChem, 2017, DOI: 10.1002/cctc.201700111.

19)    Wei Zhou, Yujun Zhao, Shengping Wang, Xinbin Ma, The Effect of Metal Properties on the Reaction Routes of Glycerol Hydrogenolysis over Platinum and Ruthenium Catalysts. Catalysis Today 298 (2017) 2-8

20)    Wei Zhou, Yujun Zhao, Yue Wang, Shengping Wang, and Xinbin Ma*, Glycerol Hydrogenolysis to 1,3-Propanediol on Tungstate/Zirconia-Supported Platinum: Hydrogen Spillover Facilitated by Pt(111) Formation, ChemCatChem 2016, 8, 3663 – 3671.

21)    S.P. Wang, S.S. Fan, Y.J. Zhao, L.J. Fan, S.Y. Liu, X.B Ma. Carbonation Condition and Modeling Studies of Calcium-Based Sorbent in the Fixed-Bed Reactor. Ind Eng Chem Res. 2014. doi10.1021/ie500789g

22)    Y.L. Meng, T. Wang, S. Chen, Y.J. Zhao, X.B. Ma, J.L. Gong. Selective oxidation of methanol to dimethoxymethane on V2O5–MoO3/γ-Al2O3 catalysts. Appl. Catal. B, 2014; 160-161(0):161-172.

23)    J.L. Gong, H.R. Yue, Y.J. Zhao, S. Zhao, L. Zhao, J. Lv, S.P. Wang, X.B. Ma, Synthesis of Ethanol via Syngas on Cu/SiO2 Catalysts with Balanced Cu0–Cu+ Sites, Journal of the American Chemical Society, 134 (2012) 13922-13925.

24)    H.R. Yue, Y.J Zhao, S. Zhao, B. Wang, X.B. Ma, J.L. Gong, A copper-phyllosilicate core-sheath nanoreactor for carbon–oxygen hydrogenolysis reactions, Nat Commun, 4 (2013). 2339 doi10.1038/ncomms3339.

25)    H.R. Yue, Y.J. Zhao, L. Zhao, J. Lv, S.P. Wang, J.L. Gong, X.B. Ma, Hydrogenation of dimethyl oxalate to ethylene glycol on a Cu/SiO2/cordierite monolithic catalyst: Enhanced internal mass transfer and stability, AIChE Journal, 58 (2012) 2798-2809.

26)    H.R. Yue, Y.J. Zhao, X.B. Ma, J.L. Gong, Ethylene glycol: properties, synthesis, and applications, Chem. Soc. Rev., 41 (2012) 4218-4244.

27)    L. Zhao, Y.J. Zhao, S.P. Wang, H.R. Yue, B. Wang, J. Lv, X.B. Ma, Hydrogenation of Dimethyl Oxalate Using Extruded Cu/SiO2 Catalysts: Mechanical Strength and Catalytic Performance, Ind Eng Chem Res, 51 (2012) 13935-13943.

28)    S. Zhao, H.R. Yue, Y.J. Zhao, B. Wang, Y.C. Geng, J. Lv, S.P. Wang, J.L. Gong, X.B. Ma, Chemoselective synthesis of ethanol via hydrogenation of dimethyl oxalate on Cu/SiO2: Enhanced stability with boron dopant, J Catal, 297 (2013) 142-150.

29)    X.B. Ma, H.W. Chi, H.R. Yue, Y.J. Zhao, Y. Xu, J. Lv, S.P. Wang, J.L. Gong, Hydrogenation of dimethyl oxalate to ethylene glycol over mesoporous Cu-MCM-41 catalysts, AIChE Journal, 59 (2013) 2530-2539.

30)    S.P. Wang, H.L. Shen, S.S. Fan, Y.J. Zhao, X.B. Ma, J.L. Gong, Enhanced CO2 adsorption capacity and stability using CaO-based adsorbents treated by hydration, AIChE Journal, 59 (2013) 3587-3593.

31)    Y. Xu, W.J. Dou, Y.J. Zhao, G.X. Huang, X.B. Ma, Kinetics Study for Ion-Exchange-Resin Catalyzed Hydrolysis of Methyl Glycolate, Ind Eng Chem Res, 51 (2012) 11653-11658.

32)    S.P. Wang, L. Zhao, W. Wang, Y.J. Zhao, G. Zhang, X.B. Ma, J.L. Gong, Morphology control of ceria nanocrystals for catalytic conversion of CO2 with methanol, Nanoscale, 5 (2013) 5582-5588.

33)    Y.Y. Dong, S.Y. Huang, S.P. Wang, Y.J Zhao, J.L. Gong, X.B. Ma, Synthesis of Dimethyl Carbonate through Vapor-Phase Carbonylation Catalyzed by Pd-Doped Zeolites: Interaction of Lewis Acidic Sites and Pd Species, Chemcatchem, 5 (2013) 2174-2177.

34)    S. Chen, Y.L. Meng, Y.J. Zhao, X.B. Ma, J.L. Gong, Selective Oxidation of Methanol to Dimethoxymethane over Mesoporous Al-P-V-O Catalysts, AIChE Journal, 59 (2013) 2587-2593.

35)    S.P. Wang, X. Zhang, Y.J. Zhao, Y.D. Ge, J. Lv, B. Wang, X.B. Ma, Pd-Fe/α-Al2O3/cordierite monolithic catalysts for the synthesis of dimethyl oxalate: effects of calcination and structure, Front. Chem. Sci. Eng., 6 (2012) 259-269.

36)    Y.D. Ge, Y.Y. Dong, S.P. Wang, Y.J. Zhao, J. Lv, X.B. Ma, Influence of crystalline phase of Li-Al-O oxides on the activity of Wacker-type catalysts in dimethyl carbonate synthesis, Front. Chem. Sci. Eng., 6 (2012) 415-422.

37)    X.C. Gao, Y.J. Zhao, S.P. Wang, Y.L. Yin, B. Wang, X.B. Ma, A Pd-Fe/alpha-Al2O3/cordierite monolithic catalyst for CO coupling to oxalate, Chemical Engineering Science, 66 (2011) 3513-3522.

38)    Y.J. Zhao, J. Zhou, J.G. Zhang, D.Y. Li, S.D. Wang, Selective hydrogenation of benzene to cyclohexene on a Ru/Al2O3/cordierite monolithic catalyst: Effect of mass transfer on the catalytic performance, Ind Eng Chem Res, 47 (2008) 4641-4647.

39)    Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Liquid-phase selective hydrogenation of benzene to cyclohexene on Ru/Al2O3-ZrO2/cordierite monolithic catalysts, J Mol Catal a-Chem, 309 (2009) 35-39.

40)    Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Preparation and Characterization of Ru/Al2O3/Cordierite Monolithic Catalysts for Selective Hydrogenation of Benzene to Cyclohexene, Catal Lett, 131 (2009) 597-605.

41)    Y.J. Zhao, J. Zhou, J.G. Zhang, S.D. Wang, Monolithic Ru-based catalyst for selective hydrogenation of benzene to cyclohexene, Catal Commun, 9 (2008) 459-464.

42)    J.G. Zhang, D.F. Li, Y.J. Zhao, Q.D. Kong, S.D. Wang, A Pd/Al2O3/cordierite monolithic catalyst for hydrogenation of 2-ethylanthraquinone, Catal Commun, 9 (2008) 2565-2569.

43)    赵玉军, 周谨, 张建国, 李德意, 王树东. 整体蜂窝催化剂Ru/Al2O3/Cordierite上循环式苯选择加氢制环己烯. 燃料化学学报,362008499-502.

44)    张建国, 李德伏, 赵玉军, 孔庆单, 王树东. 新型蒽醌加氢催化剂的制备及加氢性能研究. 工业催化, 2008, 16 (2): 62-65.

45)    赵玉军,赵硕,王博,吕静,马新宾. 草酸酯加氢铜基催化剂关键技术与理论研究进展, 化工进展, 32(2013): 721-731.

46)    迟涵文; 赵玉军; 王胜平; 徐艳; 吕静; 马新宾. Cu-MCM-41催化剂的制备及在草酸酯加氢制乙二醇催化性能. 化学工业与工程, 2013, 30(3): 1-6

47)    博,赵 硕,赵玉军,王胜平,马新宾,球磨时间对Cu/SiO2规整结构催化剂草酸酯加氢性能与涂层牢固度影响研究. 化学工业与工程, 2015, 32(2): 6-12.

48)    耿尧辰,赵玉军*,王胜平,马新宾,热稳定性增强的铈改性Cu/SiO2催化剂及在草酸酯加氢制乙二醇反应中的应用, 化学工业与工程,2015, 32(6):1-6

49)    杨文龙,赵玉军*,王胜平,马新宾,铜硅催化剂中层状硅酸铜的形成过程研究,化学工业与工程,2016, 33(1):1-7

50)    周维,赵玉军,马新宾,高活性Cu/SiO2 催化剂上甘油氢解制1,2-丙二醇,化工学报,2015, 6(8): 2999-3006

51)    X.B. Ma, H.R. Yue, Y.J. Zhao, J.L. Gong Hydrogenation of Dimethyl Oxalate to Fuel Ethanol over Cu/SiO2 Catalyst. The 6th Sino-Us Joint Conference of Chemical Engineering, 2011, Beijin, China.

52)    J. Lv, Y.J. Zhao, Study on an environmentally benign process of ethylene glycol production from syngas. 2010 AIChE Annual Meeting, Salt Lake City, UT, USA.

53)    H.R. Yue, L. Zhao, Y.J. Zhao, S.P. Wang, Y.L. Sun, J. Wang, J.L. Gong and X.B. Ma, Hydrogenation of Dimethyl Oxalate to Ethylene Glycol on a Cu/SiO2/Cordierite Monolithic Catalyst: Enhanced Internal Mass Transfer and Stability. 2011 AIChE Annual Meeting, Minneapolis, MN, USA.

54)    岳海荣,赵玉军,马新宾,草酸二甲酯加氢制乙二醇规整催化剂内扩散研究,2010, 第六届化学工程与生物工程年会,长沙,中国。 


2. 中国专利  


(1)     赵玉军 周佳华 马新宾 王胜平 醋酸加氢制乙醇含氮二氧化硅空心球负载铂锡催化剂及制备 201810258423.1 2018.03.27


(1)     赵玉军 武晓倩 马新宾 王胜平  用于酯类液相加氢合成脂肪醇的铜碳催化剂及其制备方法 201810227833X 2018.03.20

(2)     赵玉军 单宾 马新宾 王胜平  醋酸甲酯加氢生产乙醇的铜锌二氧化硅催化剂及其制备方法 201810207077.4 2018.03.14

(3)     赵玉军 欧阳梦瑶 马新宾 王胜平 草酸酯加氢制乙醇酸甲酯的多级孔纳米花结构Ag 催化剂, 201710522543.3 (2017.06.30)

(4)     赵玉军 郭子原 马新宾 王胜平 一种己二酸二甲酯气相加氢制备1,6-己二醇的方法 CN201710236004.3 2017.04.12

(5)     赵玉军 马新宾 王胜平 吕静 宋衍博 用于草酸酯加氢制乙醇的催化剂及制备方法 CN201510535692.4 2015.08.28B01J23/72(2006.01)I

(6)     赵玉军 马新宾 王胜平 吕静 宋衍博 两段法草酸酯加氢制备乙醇的工艺  CN201510535737.82015.08.28C07C29/149(2006.01)I

(7)     赵玉军 吕静 马新宾  曹新园 王胜平 王保伟 李振花 徐艳   用于醋酸酯加氢制乙醇的催化剂及其制备方法       ZL201210475769.X(授权)IPC: B01J29/03(2006.01)I

(8)     吕静 赵玉军 马新宾 曹新园 王胜平 王保伟 李振花 徐艳     醋酸酯加氢制乙醇的方法   ZL201210475715.3(授权)IPC: C07C31/08(2006.01)I;

(9)     马新宾,吕静,赵玉军,王胜平,王保伟,李振花,徐艳,巩金龙. 用于草酸酯加氢制乙醇的催化剂及其制备方法与应用.ZL201110227292.9(授权)B01J23/78(2006.01)I

(10)  马新宾,赵玉军,王胜平,赵国杰,余铭程,吕静,王保伟,李振花. 用于草酸酯加氢制乙二醇的催化剂及其制备方法. ZL 201010191578.1(授权)IPC: B01J23/76(2006.01)I

(11)  马新宾,赵玉军,岳海荣,王胜平,吕静,王保伟,李振花,徐艳用于草酸酯加氢制乙二醇的规整结构催化剂及其制备方法. ZL 201010207694.8(授权)IPC: B01J23/72(2006.01)I

(12)  马新宾,赵玉军,王保伟,吕静,王胜平,李振花,徐艳. 使用规整催化剂由CO气相偶联合成草酸酯的生产方法. ZL 201010191579.6(授权)

(13)  马新宾,高晓晨,赵玉军,王保伟,王胜平,吕静,李振花,徐艳. CO气相偶联合成草酸酯的规整催化剂及其制备方法. ZL 201010191580.9(授权)

(14)  王树东,赵玉军,周谨. 用于苯加氢制环己烯的整体催化剂及其制备方法. ZL200710064614.6(授权)

(15)  王树东,赵玉军,周谨. 使用整体催化剂由苯选择加氢制环己烯的生产方法. CN200710012575.5

(16)  黄守莹; 马新宾; 闫冰; 王胜平; 赵玉军; 蒸氨法制备铜基催化剂及其在氧化羰基化合成烷基碳酸酯中的应用,CN201210594946.6

(17)  巩金龙; 孟亚利; 马新宾; 陈爽; 赵玉军; 王胜平; 甲醇选择性氧化合成二甲氧基甲烷的负载型氧化钼催化剂及应用, CN201210330499.3

(18)  吕静; 李振花; 马新宾; 王胜平; 赵玉军; 曹新原; 由氢氧化钙羰基化制备甲酸钙的连续生产工艺,CN201310061028.1

 


3. 国际专利 

(1)     Xinbin Ma, Yujun Zhao, Shengping Wang, Jing Lv, Baowei Wang, Zhenhua Li, Yan Xu, Copper hydrogenation catalyst, especially for converting oxalate to ethylene glycol, method of preparing the catalyst and applications thereof, US 13723221

(2)     Xinbin Ma, Yujun Zhao, Baowei Wang, Shengping Wang, Jing Lv, Zhenhua Li, Monolithic structured catalyst for carbon monoxide gase-phase coupling to dialkyl oxalate & preparation method and application thereof, US 13701508

(3)     Xinbin Ma, Jing Lv, Yujun Zhao, Shengping Wang, Baowei Wang, Zhenhua Li, Yan Xu, Gong jinlong, Catalyst for hydrogenation of oxalic ester to ethanol, method of preparing the catalyst, and method of using the same, US 9029285B2

(4)     Xinbin Ma, Jing Lv, Yujun Zhao, Shengping Wang, Baowei Wang, Zhenhua Li, Yan Xu, Gong jinlong, Catalyst for ethanol production via hydrogenation of oxalate and preparation method and use thereof, EP2636448

(5)     马新宾 赵玉军 王保伟 王胜平 吕静 李振花,CO気相カップリングによるシュウ酸塩の合成に用いるモノリス構造体触媒とその調製方法、およびそれを用いたシュウ酸塩の製造方法, JP 5947792

(6)     Xinbin Ma, Yujun Zhao, Baowei Wang, Shengping Wang, Jing Lv, Zhenhua Li, Monolithic structured catalyst for carbon monoxide gase-phase coupling to dialkyl oxalate & preparation method and application thereof, IN 291884

(7)     Xinbin Ma, Yujun Zhao, Shengping Wang, Jing Lv, Baowei Wang, Zhenhua Li, Yan Xu, Catalyst having monolithic structure for manufacturing ethylene glycol by oxalate hydrogenation, preparation method and application thereof, EP11797608.4

(8)     Xinbin Ma, Yujun Zhao, Shengping Wang, Jing Lv, Baowei Wang, Zhenhua Li, Yan Xu, Catalyst having monolithic structure for manufacturing ethylene glycol by oxalate hydrogenation, preparation method and application thereof, IN 503/CHENP/2013

(9)     Xinbin Ma, Jing Lv, Yujun Zhao, Shengping Wang, Baowei Wang, Zhenhua Li, Yan Xu, Gong jinlong, Catalyst for ethanol production via hydrogenation of oxalate and preparation method and use thereof, IN4616/CHENP/2013